Only A Trillion (1957) is the first collection of essays that Asimov ever had published. They are not from his Magazine of Fantasy and Science Fiction essays, which starts with Fact and Fancy (1962).
Only A Trillionconsists of 10 essays and two faux science articles.
Here's the table of contents, and I'll start by discussing the very first essay, "The Atoms That Vanish", tomorrow.
1. The Atoms That Vanish
2. The Explosions Within Us
3. Hemoglobin and the University
4. Victory on Paper
5. The Abnormality of Being Normal
6. Planets Have an Air About Them
7. The Unblind Workings of Chance
8. The Trapping of the Sun
9. The Sea-Urchin and We
10. The Sound of Panting
11. The Marvelous Properties of Thiotimoline
12. Pate De Foix Gras