Do a search on Isaac Asimov on Ebay and you'll come up with at least 4,000 lots on which to buy or bid on.
Here's my search link for today:
It's possible to acquire a lot of Isaac's books this way, most of them quite cheaply.
(And in some senses this is a pity. When I put together my mismatched set of his F & SF essay books, at least half of them turned out to be deaccessioned library books.)